Voltammetry is a method for determining the chemical makeup of a
sample substance by measuring electrical activity, or the accumulation of
chemicals, on electrodes placed in the substance.
Stripping Voltammetry is an analytical technique that is used to detect
trace metals like arsenic, cadmium, lead, or mercury. These metals are
usually toxic to humans and animals (and plants in some cases). It does
not detect metals such as sodium, potassium, calcium and magnesium.
It works by electroplating these metals onto an electrode. This
concentrates the metals. The metals on the electrode are then
sequentially stripped off, which generates a current that can be
measured.
- The current is proportional to the amount of metal being stripped
off.
- The potential (voltage) at which the metal is stripped off is
characteristic for each metal.
This means the metals can be identified, as well as quantified.
This diagram shows how different metals can be identified at different
voltages.