The metals must be dissolved in water. For effluents, the metal is already
in solution (though some sample types may still require a digestion), but
soil samples need to have the metal extracted.
The liquid sample s added into a supporting electrolyte (buffer) to ensure
the oxidation states of the metal ions are optimised. This also dilutes the
sample, which removes many of the potentially interfering compounds.
Another component of the buffer removes any dissolved oxygen in the
sample that might interfere with the analysis.
A standard is used to confirm that the analyser is working correctly.
The sample is then added to the cell and the metals electroplated onto
the electrode at the correct voltage or potential. Not all of the metal in
solution is plated onto the electrode, but the plating time is long enough
to reduce sufficient metal onto the electrode to give a good signal.
During the plating process, the sample is mixed at high speed. This
ensures that the metal ion concentration at the electrode/sample
interface is the same as the concentration in the bulk sample.
The potential is then altered in a controlled way and the metals are
stripped from the electrode. Each metal will strip from the electrode at a
specific potential, which allows for identification of a metal.
The current generated by stripping is proportional to the metal
concentration on the electrode.
The data can be plotted to give a graph of current against potential. This
graph is called a voltammogram.