How We Analyse Metals?

How We Analyse Metals?

 The metals must be dissolved in water. For effluents, the metal is already in solution (though some sample types may still require a digestion), but soil samples need to have the metal extracted. The liquid sample s added into a supporting electrolyte (buffer) to ensure the oxidation states of the metal ions are optimised. This also dilutes the sample, which removes many of the potentially interfering compounds. Another component of the buffer removes any dissolved oxygen in the sample that might interfere with the analysis. A standard is used to confirm that the analyser is working correctly. The sample is then added to the cell and the metals electroplated onto the electrode at the correct voltage or potential. Not all of the metal in solution is plated onto the electrode, but the plating time is long enough to reduce sufficient metal onto the electrode to give a good signal. During the plating process, the sample is mixed at high speed. This ensures that the metal ion concentration at the electrode/sample interface is the same as the concentration in the bulk sample. The potential is then altered in a controlled way and the metals are stripped from the electrode. Each metal will strip from the electrode at a specific potential, which allows for identification of a metal. The current generated by stripping is proportional to the metal concentration on the electrode. The data can be plotted to give a graph of current against potential. This graph is called a voltammogram.
    • Related Articles

    • Mercury Onsite Monitoring in Soil and Water Samples

      CASE STUDY MERCURY ONSITE MONITORING IN SOIL AND WATER SAMPLES USING THE PDV6000 AND SOIL EXTRACTION DEVICES This report describes a field demonstration of the PDV6000 at a former mercury-cell chlor-alkali plant site containing mercury in the ground ...
    • What is Voltammetry?

      Voltammetry is a method for determining the chemical makeup of a sample substance by measuring electrical activity, or the accumulation of chemicals, on electrodes placed in the substance. Stripping Voltammetry is an analytical technique that is used ...
    • How We Quantify Samples Accurately

      As with all analytical methods there can be interference. The matrix and presence of other metals or substances can change the potential at which a metal strips from the electrode. Certain metals have similar stripping potentials so a slight shift in ...
    • Senson Evaluation of Cadmium, Lead and Copper on-site monitoring of water and soil samples

      The SENSPOL European Thematic Network aimed to enhance the development of sensors for practical applications in the abatement of water pollution. Background SENSPOL commenced in August 2000 and its role was to guide technological development of ...
    • Lead in soil: comparison of the field extraction kits and PDV6000 Analysis with ICPOES

      When selecting a portable instrument for the analysis and evaluation of contaminated land, the most important consideration is how the instrument that is selected compares with the standard fixed laboratory methods and instrumentation. The most ...